Oxidation of carbon nanotubes using for Cu(II) adsorption from aqueous solution
Vol. 128 No. 1B (2019), Original Article
Vol. 128 No. 1B (2019)

Oxidation of carbon nanotubes using for Cu(II) adsorption from aqueous solution

Original Article
https://doi.org/10.26459/hueuni-jns.v128i1B.5216
Published 2019-06-06
Nguyen Duc Vu Quyen
Chemistry Department, Hue University of Sciences, Hue University, 77 Nguyen Hue St., Hue, Vietnam
Tran Ngoc Tuyen
Chemistry Department, Hue University of Sciences, Hue University, 77 Nguyen Hue St., Hue, Vietnam
Dinh Quang Khieu
Chemistry Department, Hue University of Sciences, Hue University, 77 Nguyen Hue St., Hue, Vietnam
Dang Xuan Tin
Chemistry Department, Hue University of Sciences, Hue University, 77 Nguyen Hue St., Hue, Vietnam
Bui Thi Hoang Diem
Chemistry Department, Hue University of Sciences, Hue University, 77 Nguyen Hue St., Hue, Vietnam
Nguyen Thi My Tinh
Chemistry Department, Hue University of Sciences, Hue University, 77 Nguyen Hue St., Hue, Vietnam
Pham Thi Ngoc Lan
V Central Transportation Community College, 28 Ngo Xuan Thu St., Danang, Vietnam
PDF

Keywords

Oxidized carbon nanotubes
CuII adsorption capacity
CuII adsorption
potassium permanganate
oxidized CNTs.

How to Cite

1.
Quyen NDV, Tuyen TN, Khieu DQ, Tin DX, Diem BTH, Tinh NTM, Lan PTN. Oxidation of carbon nanotubes using for Cu(II) adsorption from aqueous solution. hueuni-jns [Internet]. 2019Jun.6 [cited 2024Nov.23];128(1B):5-12. Available from: http://222.255.146.83/index.php/hujos-ns/article/view/5216
ACM ACS APA ABNT Chicago Harvard IEEE MLA Turabian Vancouver

Download Citation

Endnote/Zotero/Mendeley (RIS) BibTeX
Crossref
Scopus
Google Scholar
Europe PMC

Abstract

Carbon nanotubes (CNTs) synthesized by chemical vapour deposition without using hydrogen were oxidized with 0.1 M potassium permanganate at 40oC for 2 hours and exhibited high CuII adsorption capacity from aqueous solution. X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), scanning electron microscope (SEM), transmission electron microscope (TEM) and nitrogen adsorption/desorption isotherms were used to characterize the oxidized CNTs. After oxidizing, the obtained CNTs were used to remove CuII from aqueous solution. With CuII initial concentration of 20 mg.L-1, at pH of 4 and adsorbent dosage of 0.2 g.L-1, the oxidized CNTs exhibited high CuII adsorption ability with maximum adsorption capacity of 174.4 mg.g-1.
https://doi.org/10.26459/hueuni-jns.v128i1B.5216
PDF

References

  1. Islam MS, Ahmed MK, Raknuzzaman M, Habibullah -Al- Mamun M, Islam MK. Heavy metal pollution in surface water and sediment: A preliminary assessment of an urban river in a developing country. Ecological Indicators. 2015 01;48:282-291.
  2. Li YH, Luan Z, Xiao X, Zhou X, Xu C, Wu D and Wei B. Removal of Cu2+ Ions from Aqueous Solutions by Carbon Nanotubes. Adsorption Science & Technology. 2003;21(5):475-485.
  3. Kobya M, Demirbas E, Senturk E, Ince M. Adsorption of heavy metal ions from aqueous solutions by activated carbon prepared from apricot stone. Bioresource Technology. 2005;96(13):1518-1521.
  4. Kılıç M, Kırbıyık Ç, Çepelioğullar Ö, Pütün AE. Adsorption of heavy metal ions from aqueous solutions by bio-char, a by-product of pyrolysis. Applied Surface Science. 2013;283:856-862.
  5. Alinnor I. Adsorption of heavy metal ions from aqueous solution by fly ash. Fuel. 2007 03;86(5-6):853-857.
  6. Moosa AA, Ridha AM, Abdullha IN. Chromium ions removal from wastewater using carbon nanotubes. International Journal for Innovative Research in Science & Technology. 2015;4(2):275-282.
  7. Stafiej A, Pyrzynska K. Adsorption of heavy metal ions with carbon nanotubes. Separation and PurificationTechnology. 2007;58:49-52.
  8. Atieh MA, Bakather OY, Al-Tawbini B, Bukhari AA, Abuilaiwi FA, Fettouhi MB. Effect of Carboxylic Functional Group Functionalized on Carbon Nanotubes Surface on the Removal of Lead from Water. Bioinorganic Chemistry and Applications. 2010;2010:1-9.
  9. Sui XM, Giordani S, Prato M, Wagner H. Effect of carbon nanotube surface modification on dispersion and structural properties of electrospun fibers. Applied Physics Letters. 2009;95,233113(1-3).
  10. Zehua Q and Guojian W. Effective Chemical Oxidation on the Structure of Multiwalled Carbon Nanotubes. Journal of Nanoscience and Nanotechnology. 2012;12:105-111.
  11. Scheibe B, Palen EB, Kalenczuk RJ. Oxidation and reduction of multiwalled carbon nanotubes preparation and characterization. Materials Characterization. 2010;61:185-191.
  12. Zhang N, Xie J and Varadan VK. Functionalization of carbon nanotubes bys potassium permanganate assisted with phase transfer catalyst. Smart Materials and Structures. 2014;11:962-965.
  13. Datsyuk V, Kalyva M, Papagelis K, Parthenios J, Tasis D, Siokou A, Kallitsis I, Galiotis C. Chemical oxidation of multiwalled carbon nanotubes. Carbon. 2008;46(6):833-840.
  14. Lu C and Liu C. Removal of nickel(II) from aqueous solution by carbon nanotubes. Journal of Chemical Technology and Biotechnology. 2006;81:1932-1940.
  15. Li YH, Wang S, Luan Z, Ding J, Xu C, Wu D. A dsorption of cadmium(II) from aqueous solution by surface oxidized carbon nanotubes. Carbon. 2003;41:1057-1062.
  16. Sheng G, Li J, Shao D, Hu J, Chen C, Chen Y, Wang X. Adsorption of copper(II) on multiwalled carbon nanotubes in the absence and presence of humic or fulvic acids. Journal of Hazardous Materials. 2010;178:333-340.
  17. Wang J, Li Z, Li S, Qi W, Liu P, Liu F, Ye Y, Wu L, Wang L, Wu W. Adsorption of Cu(II) on oxidized multi-walled carbon nanotubes in the presence of hidroxylated and carboxylated fullerenes. Plos one. 2013;8(8):1-11.
  18. Slobodian P, Riha P, Olejnik R, Cvelbar U, Saha P. Enhancing effect of KMnO4 oxidation of carbon nanotubes network embedded in elastic polyurethane on overall electro-mechanical properties of composite. Composites Science and Technology. 2013;81:54-60.
  19. Li YH, Di ZC, Luan ZK, Dinh J, Zuo H, Wu X Q, Xu CL, Wu DH. Removal of heavy metals from aqueous solution by carbon nanotubes: adsorption equilibrium and kinetics. Journal of Environmental Sciences. 2004 2;16:208-211.
  20. Srivastava S. Sorption of divalent metal ions from aqueous solution by oxidized carbon nanotubes and nanocages: a review. Advanced Materials Letters. 2013;4(1):2-8.
Creative Commons License

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Copyright (c) 2019 Array