Synthesis of FexZn1-xCr2O4 brown ceramic pigment by starch-assisted sol-gel process
Vol. 128 No. 1B (2019), Original Article
Vol. 128 No. 1B (2019)

Synthesis of FexZn1-xCr2O4 brown ceramic pigment by starch-assisted sol-gel process

Original Article
https://doi.org/10.26459/hueuni-jns.v128i1B.5245
Published 2019-06-06
Tran Ngo Tuyen
Chemistry Department, University of Sciences, Hue University, 77 Nguyen Hue St., Hue, Vietnam
Nguyen Duc Vu Quyen
Chemistry Department, Hue University of Sciences, Hue University, 77 Nguyen Hue St., Hue, Vietnam
Tran Bao Lam
Nghia Ha Junior High School, Quang Ngai city, Vietnam
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Keywords

Brown pigments
spinel
sol-gel method

How to Cite

1.
Tuyen TN, Quyen NDV, Lam TB. Synthesis of FexZn1-xCr2O4 brown ceramic pigment by starch-assisted sol-gel process. hueuni-jns [Internet]. 2019Jun.6 [cited 2024Nov.14];128(1B):13-9. Available from: http://222.255.146.83/index.php/hujos-ns/article/view/5245
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Abstract

In the present paper, the ceramic pigments FexZn1-xCr2O4 (x = 0 ¸ 1) were synthesized with the starch-assisted sol-gel method. The resulting pigments were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and CIE L*a*b* color measurement. The results show that FexZn1-xCr2O4 pigments form at sintering temperature of 1100 OC for 60 minutes. The ACr2O4 spinel (A: Zn, Fe) and FeCrO3 perovskite phase with excellent crystallinity appears. The brown color intensity increases gradually with the increase of the number of substituted Fe2+ cations. The pigments meet industrial requirements in terms of physicochemical characteristics.

https://doi.org/10.26459/hueuni-jns.v128i1B.5245
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References

  1. Shackelford JF, Alexander W. Materials Science and Engineering Handbook. CRC Press. 2001
  2. Chen XH, Zhang HT, Wang CH, Luo XG, Li PH. Effect of particle size on magnetic properties of zinc chromite synthesized by sol–gel method. Applied Physics Letters. 2002;81(23):4419-4421.
  3. Fiuza TER, Gottert D, Pereira LJ, Antunes SRM, Andrade AVC, Antunes AC, Souza ECF. Production of brown inorganic pigments with spinel structure using spent zinc-carbon batteries. Processing and Application of Ceramics. 2018;12(4):319-325.
  4. Milanez KW, Kuhnen NC, Riella HG, Kniess CT. Obtaining of ceramics pigments (Fe, Zn)Cr2O4 using waste of electroplating as raw material. Materials Science Forum. 2005;498-499:654-657.
  5. Ghosh D, Dutta U, Haque A, Mordvinova NE, Lebedev OI, Pal K, Gayen A, Seikh M, Mahata P. Ultra high sensitivity of luminescent ZnCr2O4 nanoparticles toward aromatic nitro explosives sensing. Dalton Transactions. 2018;14:1-18.
  6. Singh N, Rhee JY. Electronic structures and optical properties of Spinel ZnCr2O4. Journal of the Korean Physical Society. 2010;57(5):1233-1237.
  7. Niu X, Du W, Du W. Preparation and gas sensing properties of ZnM2O4 (M = Fe, Co, Cr). Sensors and Actuators. 2004;B99:405-409.
  8. Yazdanbakhsh M, Khosravi I, Goharshadi EK, Youssefi A. Fabrication of nanospinel ZnCr2O4 using sol–gel method and its application on removal of azo dye from aqueous solution. Journal of Hazardous Materials. 2010;684-689.
  9. Marinkovic ZV, Mancic L, Vulic P, Milosevic O. The influence of mechanical activation on the stoichiometry and defect structure of a sintered ZnO-Cr2O3 system. Materials Science Forum Online. 2004;453-454:423-428.
  10. Miranda EAC, Carvajal JFM, Baena OJR. Effect of the fuels glycine, urea and citric acid on synthesis of the ceramic pigment ZnCr2O4 by solution combustion. Materials Research. 2015;18(5):1038-1043.
  11. Gingasu D, Mindru I, Patron L, Culita DC, Moreno MC, Diamandescu L, Feder M, Oprea O. Precursor method—A nonconventional route for the synthesis of ZnCr2O4 spinel. Journal of Physics and Chemistry of Solids. 2013;74:1295-1302.
  12. Khetre SM, Chopade AU, Jadhav HV, Kulal SR, Jagadale PN, Bangale SV. Auto-combustion synthesis of nanocrystalline FeCrO3, International Conference on Nanoscience. Technology and Societal Implications. 2011.
  13. Mousavi Z, Soofiand F, Zare ME, Niasari MS, Bagheri S. ZnCr2O4 nanoparticles: facile synthesis, characterization, and photocatalytic properties. Scientific Reports. 2016:1-11.
  14. Nieves LJJ, Baena OJR, Tobon JI. Synthesis of ceramic pigments ACr2O4 using the non- conventional method of co-precipitation assisted by ultrasound and high energy milling. Open Journal of Inorganic Non-Metallic Materials. 2014;4:54-63.
  15. Peng C, Gao L. Optical and photocatalytic properties of spinel ZnCr2O4 nanoparticles synthesized by a hydrothermal route. Journal of the American Ceramic Society. 2008;91(7):2388-2390.
  16. Tajizadegan H, Heidary A, Torabi O, Golabgir MH, Jamshidi A. Synthesis and characterization of ZnCr2O4 nanospinel prepared via homoeneous precipitation using urea hydrolysis. International Journal of Applied Ceramic Technology. 2016;13(2):289-294.
  17. Koferstein R, Walther T, Hesse D, Ebbinghaus SG. Preparation and characterization of nanosized magnesium ferrite powders by a starch-gel process and corresponding ceramics. Journal of Materials Science. 2013;48:6509-6518.
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