Synthetsis of Ni/UiO-66 with direct and indirect methods
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Keywords

UiO-66
Ni/UiO-66
vật liệu khung hữu cơ kim loại
biến tính metal-organic framework
modified

How to Cite

1.
Lê TH, Lê TTN, Nguyễn HT, Đoàn TLQ, Hồ VMH, Đinh TTT. Synthetsis of Ni/UiO-66 with direct and indirect methods. hueuni-jns [Internet]. 2022Sep.30 [cited 2024Nov.23];131(1C):95-101. Available from: http://222.255.146.83/index.php/hujos-ns/article/view/6722

Abstract

An archetypal metal-organic framework, UiO-6,6, synthesized with the solvo-thermal method, has a large specific surface area of 1071 m2·g–1. This material was modified with NiCl2 in the direct (Nix(tt)/UiO-66) and indirect (Nix(gt)/UiO-66) methods. The two modified materials were characterized by using powder X-ray diffraction, scanning electron microscopy, and infrared spectroscopy. Their crystalline and chemical structure is not much different. However, the thermal and porous properties differ from each other.

https://doi.org/10.26459/hueunijns.v131i1C.6722
PDF (Vietnamese)

References

  1. Sanderson K. Space invaders. Nature. 2007;448:746-748.
  2. Garibay SJ, Cohen SM. Isoreticular synthesis and modification of frameworks with the UiO-66 Topology. J Chem Commun. 2010;46:7700-7702.
  3. Volkringer C, Cohen SM. Generating reactive MILs: isocyanate- and isothiocyanate-bearing MILs through postsynthetic modification. J Angew Chem. 2010;49:4644-4648.
  4. Howarth AJ, Liu Y, Li P, Li Z, Wang TC, Hupp JT, et al. Chemical, thermal and mechanical stabilities of metal– organic frameworks. J Nat Rev Mater. 2016;1:15018.
  5. Cavka JH, Jakobsen S, Olsbye U, Guillou N, Lamberti C, Bordiga S, et al. A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability. J. Am.Chem. Soc. 2008;130(42):13850-13851.
  6. DeStefano MR, Islamoglu T, Garibay SJ, Hupp JT, Farha OK. Room temperature synthesis of UiO-66 and the thermal modulation of densities of defect sites. J Chem Mater. 2017;29(3):1357-1361.
  7. Chavan S, Vitillo JG, Uddin MJ, Bonino F, Lamberti C, Groppo E, et al. Functionalization of UiO-66 metal-organic framework and highly cross-linked polystyrene with Cr(CO)3: In situ formation, stability and photoreactivity. J Chem Mater. 2010; 22:4602-4611.
  8. Thu PT, Liên PT, Lê NTH, Hường NT, Bình NT. Nghiên cứu độ bền và tính chất của vật liệu khung cơ kim Zr-MOF trong nước định hướng cho ứng dụng hấp phụ khí. Tạp chí Khoa học và Công nghệ. 2016;54(1A):128-135.
  9. Hải NĐ, Tân VM, Cảnh ĐH, Tuyến NĐ. Nghiên cứu tổng hợp vật liệu khung hữu cơ kim loại chứa zirconium với khuyết tật mạng tinh thể. Tạp chí Khoa học và công nghệ. 2018;45:86-89.
  10. Hoa LT, Nhi LTT, Sơn LVT, Linh NLM, Hai HVM, Khieu DQ. Single-Atom Ni Heterogeneous Catalysts Supported UiO-66 Structure: Synthesis and Catalytic Activities. Journal of Nanomaterials. 2021;2021:6648704
  11. Nhi LTT, Thi NM, Hải NTT, Thanh ĐTT, Hòa LT. Tổng hợp vật liệu khung hữu cơ kim loại UiO-66. Tạp chí Khoa học và công nghệ trường Đại học Khoa học. 2021;19(2):1-8.
  12. Abid HR, Pham GH, Ang HM, Tade MO, Wang S. Adsorption of CH4 and CO2 on Zr-metal organic frameworks. J Colloid Interf Sci. 2012;366:120-124.
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