Bi-metalic ZIFs(Zn-M) (M: Co, Ni) for photocatalytic removal of organic pollutants in aqueous solutions
Vol. 132 No. 1B (2023), Original Article
Vol. 132 No. 1B (2023)

Bi-metalic ZIFs(Zn-M) (M: Co, Ni) for photocatalytic removal of organic pollutants in aqueous solutions

Original Article
https://doi.org/10.26459/hueunijns.v132i1B.6886
Published 2023-06-30
Hoang Phuc Nguyen
Graduate University of Science and Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
Thanh Nhan Nguyen
Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
Soo-Wohn Lee
Department of Environmental & Bio-Chemical Engineering, Sun Moon University, Asan, South Korea
Anh Son Pham
Department of Inorganic Chemistry, VNU University of Science, Vietnam National University, Hanoi, 19 Le Thanh Tong, Hoan Kiem, Hanoi, Vietnam
Hoang Mai Ha*
Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
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Keywords

ZIF(Zn-Co)
bimetallic ZIF
photocatalytic removal
indigo carmine
organic pollutant

How to Cite

1.
Nguyen HP, Nguyen TN, Lee S-W, Pham AS, Hoang MH. Bi-metalic ZIFs(Zn-M) (M: Co, Ni) for photocatalytic removal of organic pollutants in aqueous solutions. hueuni-jns [Internet]. 2023Jun.30 [cited 2024Nov.14];132(1B):15-21. Available from: http://222.255.146.83/index.php/hujos-ns/article/view/6886
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Abstract

In this study, we successfully synthesised bi-metallic ZIF(Zn-M) of 2-methyl imidazole with a second metal (cobalt or nickel) binding to the ZIF network. All ZIF samples were synthesised at room temperature and characterised by using XRD, FT-IR, SEM, DRS, and nitrogen adsorption and desorption isotherms. The materials have high crystallinity with a large surface area. The materials’ photocatalytic ability was examined via the degradation of indigo carmine under a sun-light simulator. The second metal enhanced the photon harvesting ability of ZIF(Zn) because the materials can absorb photons in both UV and visible regions. Of the two catalysts, ZIF(Zn-Co) exhibited high photocatalytic ability when it removed 100% of indigo carmine from an aqueous solution. The catalyst adsorbed 45% of indigo carmine after 2 h and entirely degraded the remaining dye dring 1.5 h of solar irradiation. While Co2+ increased the catalyst’s surface area, Ni2+ reduced it, leading to lower photocatalytic efficiency.

https://doi.org/10.26459/hueunijns.v132i1B.6886
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References

  1. Howarth AJ, Liu Y, Li P, Li Z, Wang TC, Hupp JT, Farha OK. Chemical, thermal and mechanical stability of metal-organic frameworks. Nat Rev Mater. 2016; 1(15018):1-16.
  2. Furukawa H, Cordova KE, O’Keeffe M, Yaghi OM. The Chemistry and Applications of Metal-Organic Frameworks. Science. 2013; 341(6149):1230444.
  3. Anh Phan, Christian J. Doonan, Fernando J. Uribe-Romo, Carolyn B. Knobler MO, Yaghi OM. Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks. Acc Chem Res. 2010; 43(1):58-67.
  4. Jiang JQ, Yang CX, Yan XP. Zeolitic Imidazolate Framework-8 for Fast Adsorption and Removal of Benzotriazoles from Aqueous Solution. ACS Appl Mater Interfaces. 2013; 5(19):9837-42.
  5. Jung BK, Jun JW, Hasan Z, Jhung SH. Adsorptive removal of p-arsanilic acid from water using mesoporous zeolitic imidazolate framework-8. Chem Eng J. 2015; 267:9-15.
  6. Khan NA, Jung BK, Hasan Z, Jhung SH. Adsorption and removal of phthalic acid and diethyl phthalate from water with zeolitic imidazolate and metal-organic frameworks. J Hazard Mater. 2015; 282:194-200.
  7. Wu Y, Zhou M, Zhang B, Wu B, Li J, Qiao J. Amino acid assisted templating synthesis of hierarchical zeolitic imidazolate framework-8 for efficient arsenate removal. Nanoscale. 2014; 6:1105-12.
  8. Huan-Ping J, Chong-Chen W, Yi-Wen Z, Peng W, Ran L. Photocatalytic Degradation of Methylene Blue in ZIF-8. RSC Adv. 2014; 4:54454-62.
  9. Staffan S. Critical Evalutation of Stability Constants of metal-imidazole and metal-histamine systems. Pure Appl Chem. 1999; 69(7):1549-70.
  10. Wu R, Qian X, Zhou K, Wei J, Lou J, Ajayan PM. Porous Spinel ZnxCo3-xO4 Hollow Polyhedra Templated for High-Rate lithium-ion batteries. ACS Nano. 2014; 8(6):6297-303.
  11. Kui Z, Bibimaryam M, Zhixiong L, Shophot P, Somboon C, Francis V. Characterization and properties of Zn/Co zeolitic imidazolate frameworks vs. ZIF-8 and ZIF-67. J Mater Chem A. 2017; 5(3):952-957
  12. Fu YY, Yang CX, Yan XP. Fabrication of ZIF-8@SiO2 core-shell microspheres as the stationary phase for high-performance liquid chromatography. Chemistry. 2013; 19(40):13484-91.
  13. Bustamante EL, Fernández JL, Zamaro JM. Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 ( ZIF-8 ) nanocrystals at room temperature. J Colloid Interface Sci. 2014; 424:37–43.
  14. Housecroft CE, Sharpe AG, Catherine EH, Alan GS. Inorganic Chemistry (4th Edition). Harlow England: Pearson; 640-650.
  15. Mphuthi LE, Erasmus E, Langner EHG. Metal Exchange of ZIF-8 and ZIF-67 Nanoparticles with Fe(II) for Enhanced Photocatalytic Performance. ACS Omega. 2021; 6(47):31632-45.
  16. Sámano-Alonso C, Hernández-Obregón J, Cabrera R, Díaz-Góngora JAI, Reguera E. Tuning the adsorption potential. Separation of aromatic hydrocarbons by cobalt and zinc zeolitic imidazolate frameworks. Colloids Surfaces A Physicochem Eng Asp. 2016;506:50-5.
  17. Gurpreet K, Rohit KR, Deepika T, Xin Y, Pei-Zhou L, Xin-Chun Y, Yanli Z, Qiang X, Sanjay KS. Room-temperature synthesis of bimetallic Co-Zn based Zeolitic Imidazolate Frameworks in water for enhanced CO2 and H2 uptakes. J Mater Chem A. 2016; 4:14932-8.
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