Simultaneous determination of lead and cadmium in aqueous sources by anodic stripping voltammetry method using BiF/ErGO-GCE modified electrode
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Keywords

BiF/ErGO-GCE
determination of Cd(II) and Pb(II) and DP-ASV method BiF/ErGO
Xác định đồng thời Cd(II) và Pb(II) và phương pháp DP-ASV

How to Cite

1.
Luyện N Đình, Trang HT, Vũ HXA, Phong NH. Simultaneous determination of lead and cadmium in aqueous sources by anodic stripping voltammetry method using BiF/ErGO-GCE modified electrode. hueuni-jns [Internet]. 2024Mar.29 [cited 2024Nov.23];133(1A):23-30. Available from: http://222.255.146.83/index.php/hujos-ns/article/view/7335

Abstract

At present, the differential pulse anodic stripping voltammetry (DP-ASV) method using modified electrodes is considered as a robust method with high selectivity, sensitivity and low cost. In this study, the glassy carbon electrode was modified with reduced graphene oxide combined with a film bismuth in-situ (BiF/ErGO-GCE) to simultaneously determine Cd(II) and Pb(II) in aqueous source. Several parameters were studied including the amount of graphene oxide material, the concentration of Bi(III) and the parameters of the DP-ASV method. The detection limits of Cd(II) and Pb(II) were determined to be 1.50 ppb and 1.39 ppb. In addition, BiF/ErGO-GCE modified electrode was also applied to simultaneously determine Cd(II) and Pb(II) in two water samples of Huong and An Cuu rivers. The results were compared to those of inductively coupled plasma mass spectrometry method with sactifaction.

https://doi.org/10.26459/hueunijns.v133i1A.7335
PDF (Vietnamese)

References

  1. Saeed AA, Singh B, Nooredeen Abbas M, Dempsey E. Evaluation of Bismuth Modified Carbon Thread Electrode for Simultaneous and Highly Sensitive Cd (II) and Pb (II) Determination. Electroanalysis. 2016;28(9):2205-2213.
  2. Valasques GS, dos Santos AMP, de Souza VS, Teixeira LSG, Alves JPS, de Jesus Santos M, et al. Multivariate optimization for the determination of cadmium and lead in crude palm oil by graphite furnace atomic absorption spectrometry after extraction induced by emulsion breaking. Microchemical Journal. 2020;153:104401.
  3. Altunay N, Elik A, Bingöl D. Simple and Green Heat-Induced Deep Eutectic Solvent Microextraction for Determination of Lead and Cadmium in Vegetable Samples by Flame Atomic Absorption Spectrometry: a Multivariate Study. Biological Trace Element Research. 2020;198(1):324-31.
  4. Mohammed Nawi A, Chin S-F, Jamal R. Jamal Simultaneous analysis of 25 trace elements in micro volume of human serum by inductively coupled plasma mass spectrometry (ICP-MS). Practical Laboratory Medicine. 2020;18:e00142.
  5. Oularbi L, Turmine M, El Rhazi M. Preparation of novel nanocomposite consisting of bismuth particles, polypyrrole and multi-walled carbon nanotubes for simultaneous voltammetric determination of cadmium(II) and lead(II). Synthetic Metals. 2019;253:1-8.
  6. Yıldız C, Eskiköy Bayraktepe D, Yazan Z. Highly sensitive direct simultaneous determination of zincII, cadmiumII, leadII, and copperII based on in-situ-bismuth and mercury thin-film plated screen-printed carbon electrode. Monatshefte für Chemie - Chemical Monthly. 2021;152(12):1527-37.
  7. Wang J. Stripping Analysis: Principles, Instrumentation and applications. New York: VCH Publishers Inc; 1985.
  8. Baghayeri M, Alinezhad H, Fayazi M, Tarahomi M, Ghanei-Motlagh R, Maleki B. A novel electrochemical sensor based on a glassy carbon electrode modified with dendrimer functionalized magnetic graphene oxide for simultaneous determination of trace Pb(II) and Cd(II). Electrochimica Acta. 2019;312:80-8.
  9. Marcano DC, Kosynkin DV, Berlin JM, Sinitskii A, Sun Z, Slesarev A, et al. Improved Synthesis of Graphene Oxide. ACS Nano. 2010;4(8):4806-14.
  10. Rocha DP, Dornellas RM, Cardoso RM, Narciso LCD, Silva MNT, Nossol E, et al. Chemically versus Electrochemically Reduced Graphene Oxide: Improved amperometric and voltammetric sensors of phenolic compounds on higher roughness surfaces. Sensors and Actuators B: Chemical. 2018;254:701-8.
  11. Liu F, Huang W, Zhang Z, Zhang C, Huang Q, Xiang G, et al. Simultaneous detection of Cd2+ and Pb2+ with a bismuth flm/sulfur and nitrogen co-doped porous graphene electrode. International Journal of Electrochemical Science. 2021;16(6):210610.
  12. Horwitz W, Albert R. Quality issues the concept of uncertainty as applied to chemical measurements. Analyst. 1997;122(6):615-7.
  13. Bộ TN&MT. Quy chuẩn kỹ thuật quốc gia về chất lượng nước mặt. QCVN 08MT:2015/BTNMT. Hà Nội; 2015
  14. Zhu X, Liu B, Chen S, Wu L, Yang J, Liang S, et al. Ultrasensitive and simultaneous electrochemical determination of Pb2+ and Cd2+ based on biomass derived lotus root-like hierarchical porous carbon/bismuth composite. Journal of The Electrochemical Society. 2020;167(8):087505.
  15. Kiliç HD, Kizil H. Simultaneous analysis of Pb2+ and Cd2+ at graphene/bismuth nanocomposite flm-modifed pencil graphite electrode using square wave anodic stripping voltammetry. Anal Analytical and Bioanalytical Chemistry. 2019;411(30):8113-21.
  16. Lazanas AC, Tsirka K, Paipetis AS, Prodromidis MI. 2D bismuthene/graphene modifed electrodes for the ultra-sensitive stripping voltammetric determination of lead and cadmium. Electrochimica Acta. 2020;336:135726.
  17. Scandurra A, Ruffino F, Urso M, Grimaldi MG, Mirabella S. Disposable and low-cost electrode based on graphene paper-nafon-bi nanostructures for ultra-trace determination of Pb(II) and Cd(II). Nanomaterials. 2020;10(8):1620.
  18. Bahinting SED, Rollon AP, Garcia-Segura S, Garcia VCC, Ensano BMB, Abarca RRM, et al. Bismuth flmcoated gold ultramicroelectrode array for simultaneous quantifcation of Pb(II) and Cd(II) by square wave anodic stripping voltammetry. Sensors. 2021;21(5):1811.
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